Neither of those valves is best suited to AUTOMOTIVE nitrous use, especially the first one.
Neither valve is a very good quality and will seize up after little use and the hand wheels are at a high risk of being broken off.
To make the first one SEAL (due to the bleed hole), you'll either need an INDUSTRIAL connector which wouldn't lend itself to connecting to AUTOMOTIVE type hoses or we'd have to make you a special fitting.
The 2nd valve is CO2 valve which luckily doesn't have the sealing issue and I believe it's the size we can supply an adaptor for but a MUCH better arrangement would be to replace those valves with our FlowMax valves (which we designed SPECIFICLLY for AUTOMOTIVE nitrous use, for the following reasons;
1) They will never seize up
2) It's IMPOSSIBLE to break the hand wheels off
3) Instead of rupture discs, the MaxFlow has a Safe Pressure Relief Valve for maximum safety.
http://www.noswizard.com/index.php/nitr ... valve.html